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  <front>
    <journal-meta><journal-id journal-id-type="publisher">EGQSJ</journal-id><journal-title-group>
    <journal-title>E&amp;G Quaternary Science Journal</journal-title>
    <abbrev-journal-title abbrev-type="publisher">EGQSJ</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">E&amp;G Quaternary Sci. J.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">2199-9090</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/egqsj-72-57-2023</article-id><title-group><article-title>Chronological and sedimentological investigations of the Late Pleistocene succession in Osterbylund <?xmltex \hack{\break}?> (Schleswig-Holstein, Germany)</article-title><alt-title>Chronological and sedimentological investigations</alt-title>
      </title-group><?xmltex \runningtitle{Chronological and sedimentological investigations}?><?xmltex \runningauthor{C. Thiel et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Thiel</surname><given-names>Christine</given-names></name>
          <email>cthiel-geo@gmx.de</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Kenzler</surname><given-names>Michael</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-3754-1495</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Stephan</surname><given-names>Hans-Jürgen</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Frechen</surname><given-names>Manfred</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff5">
          <name><surname>Urban</surname><given-names>Brigitte</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Sierralta</surname><given-names>Melanie</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>B4.3 Federal Seismological Survey and Nuclear Test Ban, Federal
Institute for Geosciences and Natural Resources, Stilleweg 2, 30655
Hanover, Germany</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Institute of Geography and Geology, University of Greifswald, F.-L.
Jahn-Straße 17a, 17487 Greifswald, Germany</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>independent researcher: Köhlstr. 3, 24159 Kiel, Germany</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Section S3: Geochronology, Leibniz Institute for Applied Geophysics, Stilleweg 2, 30655 Hanover, Germany</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Institute of Ecology, Leuphana University Lüneburg,
Universitätsallee 1, 21339 Lüneburg, Germany</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Christine Thiel (cthiel-geo@gmx.de)</corresp></author-notes><pub-date><day>6</day><month>March</month><year>2023</year></pub-date>
      
      <volume>72</volume>
      <issue>1</issue>
      <fpage>57</fpage><lpage>72</lpage>
      <history>
        <date date-type="received"><day>26</day><month>December</month><year>2021</year></date>
           <date date-type="rev-recd"><day>11</day><month>October</month><year>2022</year></date>
           <date date-type="accepted"><day>11</day><month>January</month><year>2023</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2023 Christine Thiel et al.</copyright-statement>
        <copyright-year>2023</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023.html">This article is available from https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023.html</self-uri><self-uri xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023.pdf">The full text article is available as a PDF file from https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d1e160">The age of the push moraine complex Wallsbüll-Böxlund,
Schleswig-Holstein, is unclear despite investigations in this area for
decades. To address the timing of formation of both the push moraine complex
and the peat and soils found in its depressions, an outcrop in Osterbylund
(OBL) was investigated. Optically stimulated luminescence and <inline-formula><mml:math id="M1" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula>
dating, as well as pollen analyses, were undertaken with the aim to correlate
the soils OBL 1 to OBL 4 to interglacials and interstadials. The
chronological studies were accompanied by detailed sedimentological
investigations. The results of the pollen analyses put the peat
unambiguously to the Eemian; the peat is equivalent to OBL 1. The overlying
sands and the other intercalated soils are to be placed into the early
Weichselian. While for OBL 2 the assignment to the Brörup interstadial
is clear, it is more difficult to clearly correlate OBL 3 and OBL 4 to an
interstadial due to poor luminescence signal resetting of the sands,
especially above OBL 4. Considering all data available, it is most likely
that OBL 3 formed during the Odderade interstadial and OBL 4 during the
Keller interstadial. From the Eemian to early Weichselian ages of the peat
and soils it is evident that the push moraine complex is of Saalian age; a
Weichselian ice margin further in the west, as assumed in other studies, can
therefore be excluded.</p>
  </abstract>
      <trans-abstract><title>Kurzfassung</title>

      <p id="d1e182">Die Altersstellung des Stauchmoränenkomplexes
Wallsbüll-Böxlund in Schleswig-Holstein ist trotz jahrzehntelanger
Untersuchungen noch ungeklärt. Die in einem Aufschluss in Osterbylund
(OBL) aufgeschlossenen Sedimente und Torfe sowie Böden wurden zur
Klärung dieser Frage und auch zur Korrelation der Böden OBL 1 bis
OBL 4 mit den bekannten Interglazialen und Interstadialen mittels optisch
stimulierter Lumineszenz und Uran-Thorium sowie Pollenanalysen datiert.
Detaillierte<?pagebreak page58?> sedimentologische Aufnahmen ergänzten die chronologischen
Arbeiten. Die Pollenanalysen ordnen den in Depressionen vorkommenden Torf
dem Eem zu; der Torf ist mit OBL 1 gleichzusetzen. Die aufliegenden Sande
und die übrigen eingeschalteten Böden können alle in das
Frühweichsel gestellt werden. Während für OBL 2 die Stellung in
das Brörup-Interstadial aufgrund der Daten belegbar ist, gestalten sich
die Zuordnungen für OBL 3 und OBL 4 etwas schwieriger, da schlechte
Bleichung der Lumineszenzsignale der Sande insbesondere oberhalb von OBL 4
Unsicherheiten mit sich bringen. Unter Berücksichtigung der Gesamtheit
der Daten ist eine Korrelation von OBL 3 mit dem Odderade-Interstadial und
von OBL 4 mit dem Keller-Interstadial am wahrscheinlichsten. Aus diesen
Daten ergibt sich zudem eine saalezeitliche Entstehung des
Stauchmoränenwalls; ein, wie in anderen Studien angenommen,
weichselzeitlicher Eisrand noch weiter westlich als der hier untersuchte
Standort kann somit ausgeschlossen werden.</p>
  </trans-abstract>
      <custom-meta-group><custom-meta><meta-name>citationstatement</meta-name><meta-value>Thiel, C., Kenzler, M., Stephan, H.-J., Frechen, M., Urban, B., and Sierralta, M.: Chronological and sedimentological investigations of the Late Pleistocene succession in Osterbylund  (Schleswig-Holstein, Germany), E&amp;G Quaternary Sci. J., 72, 57–72, https://doi.org/10.5194/egqsj-72-57-2023, 2023.</meta-value></custom-meta></custom-meta-group>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e194">The extent of the Weichselian ice sheet and the environment in the southern
Baltic region and bordering areas in northern Germany has received large
attention (e.g. Houmark-Nielson, 2010; Kenzler et al., 2017, 2018;
Rinterknecht et al., 2014). In contrast to detailed knowledge on the late
Weichselian ice dynamics and its climatic implications (e.g. Hughes et al.,
2016; Lüthgens et al., 2020), the early Weichselian in this area has not
yet been investigated in its entirety. This period, however, is especially
interesting due to the changes between cold and warm phases. While these
climate variations are well preserved in ice cores (e.g. Seierstad et al.,
2014), there is a lack of local terrestrial archives documenting the highly
variable conditions at that time.</p>
      <p id="d1e197">Among the few terrestrial sites in northern Germany where palaeosols as
indicators for warm phases are preserved is the push moraine ridge in
Osterbylund, northern Schleswig-Holstein, close to the Danish border (Fig. 1). However, whether the palaeosols represent the Weichselian remains
controversially discussed. It has been argued that the soils got deformed by
the youngest Saalian (“Warthian”) glacier advance during marine isotope
stage (MIS) 6 and had therefore been interpreted as “intra-Saalian”, with an
attribution of the lowermost and most intensively developed soil to the
intra-Saalian “Treene interglacial” (e.g. Stremme, 1981, 1986; Stremme et
al., 1982; Stremme and Weinhold, 1982; Zöller, 1986). In contrast, it has
been claimed that the soils are of post-Saalian age, with the lowermost soil
representing the Eemian interglacial, not being glacially deformed; the
overlying soils represent Weichselian interstadials (Gripp et al., 1965).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e202">Overview of the Baltic region in which the study area is located,
<bold>(a)</bold> showing the ice marginal positions of the Saalian and Weichselian glaciations and <bold>(b)</bold> the push moraine complex Wallsbüll-Böxlund; OBL <inline-formula><mml:math id="M2" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> Osterbylund.</p></caption>
        <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f01.jpg"/>

      </fig>

      <p id="d1e225">To address the debate on the age of the push moraine ridge and with it on
the palaeosol formation, optically stimulated luminescence (OSL) dating is
the method of choice, as it can be applied to the clastic sediments
underlying and covering the soils. In luminescence dating, the time elapsed
since the last exposure to daylight is determined; this is in general
referred to as the burial age. From that it is evident that not the soil
formation itself is being dated, but that age constraints can be provided.</p>
      <p id="d1e228">In our study we present detailed sedimentological investigations of the
sediment succession in the push moraine complex near Osterbylund,
Schleswig-Holstein, Germany, together with OSL ages from the sediment over- and underlying the palaeosols. In addition, pollen analyses from a peat
underlying the clastic sediments are presented together with an attempt to
date the peat using <inline-formula><mml:math id="M3" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> dating. The combination of the data is then
used to correlate the investigated strata and the palaeosols to MISs, with
the aim to add another jigsaw piece to the glacial and intraglacial
development in the western Baltic region.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Geological setting</title>
      <p id="d1e255">For decades, several sand–gravel pits have been opened in a 9 km long, SE–NW
stretching push moraine ridge between Wallsbüll and Böxlund,
northern Schleswig-Holstein, close to the Danish border (Fig. 1). Two of them
(Böxlund 1 and 2; Fig. 1b) have been intensely investigated over decades
due to the occurrence of palaeosols (e.g. Stremme and Weinhold, 1980).
Because of the presence of several organic-rich horizons, the sand–gravel
pit in Osterbylund became of special interest. It is situated on the same ridge
(Fig. 1) a few kilometres SW of the Danish border. The push moraine is
surrounded by Weichselian sandur plains originating from meltwater streams
of the Weichselian end moraines draining westwards into the North Sea. The
surfaces of these plains have an elevation no higher than <inline-formula><mml:math id="M4" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>25 m above
present sea level (a.s.l.). The Saalian push moraine complex is 20 to 30 m
higher than these plains (topographical map of Germany <inline-formula><mml:math id="M5" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>:</mml:mo><mml:mn mathvariant="normal">25</mml:mn></mml:mrow></mml:math></inline-formula> 000; sheets
Medelby, 1121, and Wallsbüll, 1221), with the highest point, called
Lundtop, reaching <inline-formula><mml:math id="M6" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>53.8 m a.s.l.</p>
      <p id="d1e284">The continuous exploitation of the pit revealed not only the complexity of
the sand succession and the intercalated soils and organic-rich horizons
but also various peat layers. Further, two folded palaeosols in
superposition were found (see Stephan, 1988). Based on detailed sedimentary
and structural studies, Stephan (1988) showed that the<?pagebreak page59?> deformation had
developed by a periglacial sheet sliding downslope with thrust folding,
probably initiated by an undercut of the moraine slope by Weichselian
meltwater streams.</p>
      <p id="d1e287">In Fig. 2, a generalised view of the sediments, structure, and deformation
is given. The lower and median parts are mainly meltwater sands, in most
cases strongly deformed by glacial pressure (folded and cut by thrust
faults). Blocks of till and folded till beds are incorporated in the sands
mostly getting smaller upwards, rarely reaching the surface. The
northeastern part of the deformed sequence is covered by a thick undulating
till sheet overlain by periglacial sands, which are several metres thick,
not deformed, and concordantly filling push synclines, upwards with slightly
undulating or increasingly even stratification. Several palaeosols (named
OBL 1–4) have been observed within these sandy deposits; the lower two soils
show distinct humus-rich Ah horizons (according to AG Boden, 2005). Towards
the centres of the synclines the lowermost humus layer is often graded into a peat.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e293">Generalised sketch of the push moraine in Osterbylund. In the
depression, the four palaeosols OBL 1 to OBL 4 are exposed (see Figs. 3 and
4).</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f02.png"/>

      </fig>

</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Field investigations</title>
      <p id="d1e311">Different outcrop walls have been investigated over the last 2 decades,
showing various sedimentological features which can be used to obtain an
integrated picture. Detailed investigations and sampling for dating and
pollen analyses were carried out in 2003, 2004, and 2005. The field studies
in 2012 (see Stephan et al., 2017) and 2016 focussed on the sedimentological
description to obtain a better understanding of the geological and
geomorphological processes at the site.</p><?xmltex \hack{\newpage}?>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Exposure and sampling in 2003</title>
      <p id="d1e322">A standardised profile of the investigated exposures (54.798216<inline-formula><mml:math id="M7" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 9.232047<inline-formula><mml:math id="M8" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E) is given in Fig. 3 (composite profile 2003).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e345">Profiles investigated in the years 2003 to 2005, indicating the
locations where samples for luminescence dating (LUM) were taken. Sample LUM
470 originates from an isolated block, which hampers the correlation.
Therefore, the sample is not marked in the profile.</p></caption>
          <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f03.jpg"/>

        </fig>

      <p id="d1e354">At the bottom, a greyish-brown till is exposed, overlain by grey sand, only
1 cm thick, upwards followed by a 1.8 m thick peat, which can be parted into
a lower black and an upper blackish-brown peat (Fig. 3). The black peat is
compact and has a platy structure, while the overlying peat shows an only
slightly platy structure but many well-preserved fragments of plants and
wood. Both peat layers were sampled for <inline-formula><mml:math id="M9" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> dating (TIMS no. <inline-formula><mml:math id="M10" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 700, Table S1 in the Supplement) and pollen analyses.</p>
      <p id="d1e381">The peat is discordantly overlain by mainly fine- to medium-grained sand;
the transition between peat and sand exhibits dislocated peat fragments. The
sand appears partly weakly podsolised, and its lamination is altered by mass
movements. About 1 m above the peat an OSL sample (LUM 498) was taken (Figs. 3, S1). The sand graded upwards into greyish silt, overlain by a
strongly disturbed mud, which is up to 15 cm thick and interbedded with
relics of an Ae horizon (Fig. 3). Above the mud, there is grey to
yellowish-grey laminated sand of about 4 m in thickness. This sand was
sampled some metres above the mud (LUM 469). At its top, a thin and slightly
humic Ah horizon is present and overlain by a brownish sand (see composite
profile 2003 in Fig. 3). One OSL sample (LUM 470) was taken from an isolated
block about 60 m to the northeast below a brown clay. The sedimentary
conditions at this site are slightly unclear; the material may belong to a
gravity flow.</p>
</sec>
<?pagebreak page60?><sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Exposure and sampling in 2004 and 2005</title>
      <p id="d1e392">The generalised profile of an exposure north of the site investigated in
2003 is presented in Fig. 3 (profiles 2005-1 and 2005-2). The same peat bed as
found in 2003 was exposed in a small incision originating from water run-off
(54.798351<inline-formula><mml:math id="M11" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 9.232048<inline-formula><mml:math id="M12" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; profile 2005-2); the
palaeosols were present at 54.798218<inline-formula><mml:math id="M13" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 9.231425<inline-formula><mml:math id="M14" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E
(profile 2005-1). All four palaeosols (OBL 1–4) were present at this
exposure (Fig. 4).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e433">Photograph of the NW-facing outcrop investigated in 2005 showing
OBL 1–OBL 4. This photograph corresponds to profile 2005-1 in Fig. 3.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f04.jpg"/>

        </fig>

      <p id="d1e442">The bottom part (profile 2005-2) is composed of a ca. 0.2 m thick very
fine-grained sand, covered by silt ca. 0.4 m in thickness. One sample for OSL
dating (LUM 1137) was taken from the sand. The silt is overlain by 1.5 m
thick peat; there, a series of samples for <inline-formula><mml:math id="M15" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> dating was taken
(TIMS no. <inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">700</mml:mn></mml:mrow></mml:math></inline-formula>; Table S1). Above the peat, most parts of the
overlying succession are dug off, with the peat forming the sole of an
excavation plane (terrace). About 40 m further to the west (profile 2005-1)
the peat graded into a thick humus layer with an underlying podsol (OBL 1 in
profile 2005-1, Fig. 3), both periglacially disturbed and partly displaced.
Above the humus layer, a 1.8 m thick mainly fine- to medium-grained,
laminated sand followed, overlain by an Ah horizon (OBL 2) with intense
podsolisation (distinct leached horizon and a thick yellow to rusty brown
Bsh horizon). Just below OBL 2, a sample for luminescence dating was taken
(LUM 1138). On top of the weak soil, there are about 2 m thick stratified
sands with few gravels; these sands are distinctly podsolised and overlain
by a thin humus layer (OBL 3). One sample for OSL dating (LUM 1139) was
taken from the leached sand (Fig. 3; profile 2005-1, Fig. S2).</p>
      <p id="d1e472">The podsol is covered by fine- to medium-grained laminated brownish sands,
which are most likely of aeolian origin. One sample for OSL dating (LUM
1140) was taken<?pagebreak page61?> 0.75 m above the podsol from the sand. This sequence was
overprinted close to the top by a thin and weak podsol with a very thin
Ah layer (OBL 4); ca. 0.2 m below this Ah layer there is an intercalation with
gravel. The gravels are polished and frequently split by frost. Above the
Ah layer laminated brownish sands, ca. 1 m in thickness, are found. These
sands are cryoturbated at the top. The cryoturbated zone has an admixture of
some gravels and few stones, evidencing transport of coarse material from
outcropping till further up the slope. The uppermost sample for OSL dating
(LUM 1141) was taken 0.5 m above the Ah layer of OBL 4.</p>
</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Exposure in 2016</title>
      <p id="d1e484">The exposure investigated in 2016 (54.798162<inline-formula><mml:math id="M17" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N,
9.230141<inline-formula><mml:math id="M18" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; Fig. 5) is located 100 m to the west of profile
2005-2.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e507">Photograph and sketches of the profiles investigated in 2016. A
detailed lithological description is given in Fig. 6 and in the main text.</p></caption>
          <?xmltex \igopts{width=406.874409pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f05.jpg"/>

        </fig>

      <p id="d1e516">Based on its sedimentological and pedological characteristics, profile
2016-2 has been subdivided into five lithological units (Unit I to V;
Fig. 6):</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e522">Detailed lithological log of profile 2016-2. The profile is
subdivided into five lithological units I to V, for which a detailed
description is given in the main text.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f06.png"/>

        </fig>

      <p id="d1e531">Unit I comprises two superimposed diamict layers, with a total thickness of
at least 1 m. The lower boundary was not visible due to slope debris. The
basal part of the outcropping strata consists of a stiff, matrix-supported
silty, greenish-grey diamicton with sporadic medium- to coarse-grained sand
lenses. The transition to the 20–30 cm thick overlying matrix-supported
sandy diamicton is gradual. Faint subhorizontally stratified domains are
visible in this uppermost greenish-grey part of unit I (Fig. 6).</p>
      <p id="d1e534">The 1.3 m thick unit II is composed of massive medium-grained sand
intercalated with granule lenses and pebble stingers in the middle part
(Figs. 6 and 7a–c). At the undulating base, a centimetre-thick faintly
developed humic layer is present, which marked the transition from unit I to
unit II. Isolated black humic spots at the centimetre scale are scattered across the basal 20 cm of unit II (OBL 1). The middle part shows rusty oxidation
domains and patchy iron staining at the decimetre scale due to accumulation of illuvial
sesquioxides and organic matter. The uppermost 20–30 cm sandy parts are
better sorted with very sporadic fine-grained gravel clasts. The sands are
leached due to intensive podsolisation. The uppermost 5–10 cm of unit II is
formed by a humic layer (OBL 2).</p>
      <p id="d1e537">The overlying 1.7 m thick unit III is characterised by medium-grained partly
deformed sand layers and a basal clayey silt lens at the  decimetre scale (Fig. 7a). The
lower sandy part is dominated by soft sediment deformation structures
recognisable by iron precipitates along lithological boundaries. Sporadic
discontinuous gravel layers occur in the middle part of the unit. The upper
part displays as intensive podsolisation marked by leached sand. Several
outsized clasts occur in the uppermost part of this unit, some of which are
broken. The top of unit III is made of a discontinuous humic layer at the millimetre to
centimetre scale (OBL 3). From the base of this humic layer subvertical sand-filled
cracks and fissures penetrate the underlying leached sand (Fig. 7c). From a
pedological point of view, unit III can be subdivided into the following
three soil horizons (Fig. 6): an up to 1.3 m thick Bsh horizon with
accumulated illuvial sesquioxides and organic material, an up to 0.4 m thick
intensively podsolised Ae horizon (leached sand), and an uppermost
discontinuous humic Ah horizon. A hiatus represents the boundary to the
overlying unit IV, which is up to 1.6 m thick and consists of massive to
faintly (sub-)horizontal stratified medium-grained sand. Iron staining is
present in the lower part along lithological boundaries. Several burrow-like
structures identifiable by colour changes are visible in the middle part
(Fig. 7b). Further features are clay bands at the millimetre scale, a faintly visible
5–10 cm thick humic layer in the lower middle part (OBL 4), and a sporadic
fine-grained gravel stringer in the upper part (Figs. 5, 6, and 7b). From the
top of this unit a wedge-shaped structure vertically penetrates  the
underlying deposits up to unit III (Figs. 6 and 7a).</p>
      <p id="d1e540">The uppermost 30 cm thick unit V is dominated by non-stratified
medium-grained sand and isolated fine- to medium-grained gravel clasts. A
significant root penetration characterises this brownish unit, which
represents the Holocene soil.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Age determination of the sands and peat</title>
      <p id="d1e552">The chronological approach is threefold: next to absolute dating of the
clastic sediments using OSL, it was attempted to date the peat using
<inline-formula><mml:math id="M19" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula>. Additionally, pollen analyses were conducted for a qualitative
allocation of the peat to possible warm phases.</p><?xmltex \hack{\newpage}?>
<?pagebreak page62?><sec id="Ch1.S4.SS1">
  <label>4.1</label><title>Optically stimulated luminescence dating</title>
      <p id="d1e579">In total, eight samples were taken for OSL dating from three different
profiles (see Table 1, Fig. 3) by hammering tubes into freshly cleaned
sediment walls. After sampling, the tubes were sealed to avoid
light exposure, and the material from immediately around the tubes was
sampled for dose rate determination.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e585">Summary of radionuclide concentrations, total dose rates (DR), and optically
stimulated luminescence information. <inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> equivalent dose, <inline-formula><mml:math id="M21" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M22" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> number
of aliquots, SE <inline-formula><mml:math id="M23" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> standard error, and <inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub><mml:mo>=</mml:mo></mml:mrow></mml:math></inline-formula> overdispersion.
The water contents used for dose rate calculation are given in the text.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="11">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="right"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="left"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
         <oasis:entry rowsep="1" namest="col6" nameend="col9" align="center">Quartz OSL </oasis:entry>
         <oasis:entry colname="col10"/>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Lab ID</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">40</mml:mn></mml:msup></mml:math></inline-formula>K <inline-formula><mml:math id="M30" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SE</oasis:entry>
         <oasis:entry colname="col3">U <inline-formula><mml:math id="M31" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SE</oasis:entry>
         <oasis:entry colname="col4">Th <inline-formula><mml:math id="M32" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SE</oasis:entry>
         <oasis:entry colname="col5">DR <inline-formula><mml:math id="M33" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SE</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M35" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SE</oasis:entry>
         <oasis:entry colname="col7"><inline-formula><mml:math id="M36" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col8"><inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M38" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SE</oasis:entry>
         <oasis:entry colname="col9">Age <inline-formula><mml:math id="M39" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> SE</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>pIRIR<inline-formula><mml:math id="M41" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">290</mml:mn></mml:msub></mml:math></inline-formula>/</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">(%)</oasis:entry>
         <oasis:entry colname="col3">(ppm)</oasis:entry>
         <oasis:entry colname="col4">(ppm)</oasis:entry>
         <oasis:entry colname="col5">(Gy ka<inline-formula><mml:math id="M42" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col6">(Gy)</oasis:entry>
         <oasis:entry colname="col7"/>
         <oasis:entry colname="col8">(%)</oasis:entry>
         <oasis:entry colname="col9">(ka)</oasis:entry>
         <oasis:entry colname="col10"><inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> OSL</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">LUM 469</oasis:entry>
         <oasis:entry colname="col2">0.75 <inline-formula><mml:math id="M44" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col3">0.51 <inline-formula><mml:math id="M45" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col4">1.45 <inline-formula><mml:math id="M46" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.05</oasis:entry>
         <oasis:entry colname="col5">0.94 <inline-formula><mml:math id="M47" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.07</oasis:entry>
         <oasis:entry colname="col6">64 <inline-formula><mml:math id="M48" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3</oasis:entry>
         <oasis:entry colname="col7">20</oasis:entry>
         <oasis:entry colname="col8">14.4 <inline-formula><mml:math id="M49" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.1</oasis:entry>
         <oasis:entry colname="col9">68 <inline-formula><mml:math id="M50" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6</oasis:entry>
         <oasis:entry colname="col10">1.50 <inline-formula><mml:math id="M51" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.09</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LUM 470</oasis:entry>
         <oasis:entry colname="col2">0.80 <inline-formula><mml:math id="M52" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col3">0.40 <inline-formula><mml:math id="M53" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col4">1.00 <inline-formula><mml:math id="M54" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.05</oasis:entry>
         <oasis:entry colname="col5">0.84 <inline-formula><mml:math id="M55" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.07</oasis:entry>
         <oasis:entry colname="col6">88 <inline-formula><mml:math id="M56" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7</oasis:entry>
         <oasis:entry colname="col7">20</oasis:entry>
         <oasis:entry colname="col8">33.4 <inline-formula><mml:math id="M57" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.2</oasis:entry>
         <oasis:entry colname="col9">104 <inline-formula><mml:math id="M58" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 12<inline-formula><mml:math id="M59" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10">7.09 <inline-formula><mml:math id="M60" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.35</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LUM 498</oasis:entry>
         <oasis:entry colname="col2">0.93 <inline-formula><mml:math id="M61" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col3">0.71 <inline-formula><mml:math id="M62" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col4">2.17 <inline-formula><mml:math id="M63" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.04</oasis:entry>
         <oasis:entry colname="col5">1.16 <inline-formula><mml:math id="M64" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.08</oasis:entry>
         <oasis:entry colname="col6">76 <inline-formula><mml:math id="M65" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4</oasis:entry>
         <oasis:entry colname="col7">20</oasis:entry>
         <oasis:entry colname="col8">14.2 <inline-formula><mml:math id="M66" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.3</oasis:entry>
         <oasis:entry colname="col9">66 <inline-formula><mml:math id="M67" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6</oasis:entry>
         <oasis:entry colname="col10">1.50 <inline-formula><mml:math id="M68" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.09</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LUM 1137</oasis:entry>
         <oasis:entry colname="col2">1.13 <inline-formula><mml:math id="M69" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col3">0.89 <inline-formula><mml:math id="M70" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col4">3.70 <inline-formula><mml:math id="M71" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col5">1.38 <inline-formula><mml:math id="M72" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.08</oasis:entry>
         <oasis:entry colname="col6"><inline-formula><mml:math id="M73" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 100<inline-formula><mml:math id="M74" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col7">12</oasis:entry>
         <oasis:entry colname="col8">33.5 <inline-formula><mml:math id="M75" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3.0</oasis:entry>
         <oasis:entry colname="col9"><inline-formula><mml:math id="M76" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 70<inline-formula><mml:math id="M77" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10">2.72 <inline-formula><mml:math id="M78" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.39</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LUM 1138</oasis:entry>
         <oasis:entry colname="col2">0.62 <inline-formula><mml:math id="M79" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col3">0.75 <inline-formula><mml:math id="M80" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col4">1.86 <inline-formula><mml:math id="M81" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col5">0.87 <inline-formula><mml:math id="M82" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.07</oasis:entry>
         <oasis:entry colname="col6">74 <inline-formula><mml:math id="M83" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3</oasis:entry>
         <oasis:entry colname="col7">20</oasis:entry>
         <oasis:entry colname="col8">4.8 <inline-formula><mml:math id="M84" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.0</oasis:entry>
         <oasis:entry colname="col9">86 <inline-formula><mml:math id="M85" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8</oasis:entry>
         <oasis:entry colname="col10">1.73 <inline-formula><mml:math id="M86" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.11</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LUM 1139</oasis:entry>
         <oasis:entry colname="col2">0.85 <inline-formula><mml:math id="M87" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col3">0.79 <inline-formula><mml:math id="M88" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col4">2.08 <inline-formula><mml:math id="M89" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
         <oasis:entry colname="col5">1.11 <inline-formula><mml:math id="M90" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.08</oasis:entry>
         <oasis:entry colname="col6">76 <inline-formula><mml:math id="M91" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4</oasis:entry>
         <oasis:entry colname="col7">12</oasis:entry>
         <oasis:entry colname="col8">13.0 <inline-formula><mml:math id="M92" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.1</oasis:entry>
         <oasis:entry colname="col9">69 <inline-formula><mml:math id="M93" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6</oasis:entry>
         <oasis:entry colname="col10">1.49 <inline-formula><mml:math id="M94" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.07</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LUM 1140</oasis:entry>
         <oasis:entry colname="col2">0.68 <inline-formula><mml:math id="M95" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col3">0.39 <inline-formula><mml:math id="M96" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col4">1.17 <inline-formula><mml:math id="M97" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col5">0.93 <inline-formula><mml:math id="M98" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.08</oasis:entry>
         <oasis:entry colname="col6">56 <inline-formula><mml:math id="M99" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 3</oasis:entry>
         <oasis:entry colname="col7">20</oasis:entry>
         <oasis:entry colname="col8">16.3 <inline-formula><mml:math id="M100" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.1</oasis:entry>
         <oasis:entry colname="col9">60 <inline-formula><mml:math id="M101" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6</oasis:entry>
         <oasis:entry colname="col10">1.78 <inline-formula><mml:math id="M102" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.24</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LUM 1141</oasis:entry>
         <oasis:entry colname="col2">0.67 <inline-formula><mml:math id="M103" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col3">0.59 <inline-formula><mml:math id="M104" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col4">1.71 <inline-formula><mml:math id="M105" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
         <oasis:entry colname="col5">1.01 <inline-formula><mml:math id="M106" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.08</oasis:entry>
         <oasis:entry colname="col6">43 <inline-formula><mml:math id="M107" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2</oasis:entry>
         <oasis:entry colname="col7">20</oasis:entry>
         <oasis:entry colname="col8">25.4 <inline-formula><mml:math id="M108" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.8</oasis:entry>
         <oasis:entry colname="col9">43 <inline-formula><mml:math id="M109" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4<inline-formula><mml:math id="M110" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col10">2.42  <inline-formula><mml:math id="M111" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.16</oasis:entry>
         <oasis:entry colname="col11"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e635"><inline-formula><mml:math id="M25" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M26" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> poorly bleached,
<inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M28" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> saturated and poorly bleached.</p></table-wrap-foot></table-wrap>

<sec id="Ch1.S4.SS1.SSS1">
  <label>4.1.1</label><title>Dose rate determination</title>
      <p id="d1e1692">The sub-samples for dose rate determination were dried at 120 <inline-formula><mml:math id="M112" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
and then manually homogenised prior to packing in Marinelli beakers
(<inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">700</mml:mn></mml:mrow></mml:math></inline-formula> g); these were tightly wrapped and stored for at least
1 month prior to counting with a high-resolution gamma spectrometer to
ensure equilibrium between radon and its daughter nuclides.</p>
      <?pagebreak page63?><p id="d1e1714"><?xmltex \hack{\newpage}?>The concentrations of uranium, thorium, and potassium as given in Table 1
were converted into sediment dose rates using the conversion factors given
in Guérin et al. (2011) and were modified by the life-time burial water
content using the expressions given in Aitken (1985). For the aeolian sands
(LUM 1140 and LUM 1141) a water content of <inline-formula><mml:math id="M114" display="inline"><mml:mrow><mml:mn mathvariant="normal">10</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> % was used. LUM
1137 originates from the sand in the depression just above the till. The
sand was water-logged most of its burial time; this made us use a water
content of <inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:mn mathvariant="normal">25</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> %. Similar conditions were most likely present in
the sands from which sample LUM 470 was taken so that we assumed the same
water content for this sample. According to the hydromorphic features
observed in the soils and sands, the other samples must have undergone
changing conditions from wet to dry, with the wet phases dominating.
Therefore, we assumed a water content of <inline-formula><mml:math id="M116" display="inline"><mml:mrow><mml:mn mathvariant="normal">17.5</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> % for the remaining
samples. The cosmic part of the dose rates was determined following Prescott
and Hutton (1994) and added to the sediment dose rate, resulting in the
total dose rates summarised in Table 1.</p>
</sec>
<sec id="Ch1.S4.SS1.SSS2">
  <label>4.1.2</label><title>Equivalent dose measurements</title>
      <p id="d1e1763">The light-proof tubes containing the sub-sample for equivalent dose
determination were opened in red light in the luminescence dating laboratory
at the Leibniz Institute for Applied Geophysics, Hanover. The outer ends of
each sample were discarded to ensure that any sediment exposed to light is
not used.</p>
      <p id="d1e1766">After dry sieving, the dominating grain size fraction  was chemically treated with hydrochloric acid (HCl), sodium oxalate, and hydrogen
peroxide in order to remove carbonates, clay remnants, and organic matter,
respectively. The samples were thoroughly washed with distilled water
between each treatment step. After drying the samples at 50 <inline-formula><mml:math id="M117" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C,
the quartz-rich fraction was separated from the potassium-rich feldspar (in
the following called K-feldspar) fraction by heavy liquid separation using
sodium polytungstate (quartz: <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">2.62</mml:mn></mml:mrow></mml:math></inline-formula> g cm<inline-formula><mml:math id="M119" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>;
K-feldspar: <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mo>≤</mml:mo><mml:mn mathvariant="normal">2.58</mml:mn></mml:mrow></mml:math></inline-formula> g cm<inline-formula><mml:math id="M121" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). The dried quartz
extracts were then purified using 40 % hydrofluoric acid for 1 h,
followed by an HCl (30 %) treatment and washing with distilled water. The
etched fractions were sieved again in order to avoid contamination with
small particles.</p>
      <p id="d1e1826">The coarse-grained quartz extracts were mounted in a single layer on stainless
steel discs as medium-sized (6 mm) aliquots using silicon oil as adhesive.
Preference would have been given to smaller aliquots (e.g. Duller, 2008);
however, the samples were not very sensitive, and we chose to increase the
aliquot size for better analytical data. The luminescence measurements were
made with automated Risø TL/OSL-DA-20 readers (Thomsen et al., 2006),
equipped with calibrated <inline-formula><mml:math id="M122" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">90</mml:mn></mml:msup><mml:mi mathvariant="normal">Sr</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">90</mml:mn></mml:msup><mml:mi mathvariant="normal">Y</mml:mi></mml:mrow></mml:math></inline-formula> beta sources allowing for in
situ beta irradiation. The quartz fractions were stimulated with an array of
blue light-emitting diodes (LEDs), and the luminescence was detected through
a 7.5 mm Hoya U-340 filter in the ultraviolet region.</p>
      <p id="d1e1848">The purity of the quartz extracts was checked by means of the IR/OSL
depletion ratio (Duller, 2003); there was no<?pagebreak page64?> significant IRSL signal present,
indicated by an IR depletion ratio within 5 % of unity. These initial
measurements also indicated fast decay of the quartz luminescence signal;
this is supported by a comparison with calibration quartz (Fig. 8a).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e1854">Detailed photographs of profile 2016-2. <bold>(a)</bold> Features of
lithological units II and III. <bold>(b)</bold> Burrow-like structures identifiable by
colour changes. <bold>(c)</bold> Base of OBL 3 with subvertical sand-filled cracks and
fissures penetrating the underlying leached sands.</p></caption>
            <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f07.jpg"/>

          </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><?xmltex \currentcnt{8}?><?xmltex \def\figurename{Figure}?><label>Figure 8</label><caption><p id="d1e1874"><bold>(a)</bold> Natural decay curve of one representative aliquot (sample LUM
1140) in comparison to calibration quartz (batch 30) showing that the quartz
OSL signal from the Osterbylund samples is dominated by the fast component.
Preheat plateaus for samples <bold>(a)</bold> LUM 498 and <bold>(b)</bold> LUM 1141. The temperatures
shown in red circles are the preheat temperatures used in the <inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
measurements and dose recovery experiments.</p></caption>
            <?xmltex \igopts{width=170.716535pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f08.png"/>

          </fig>

      <p id="d1e1902">Preheat plateau measurements were conducted on two samples (LUM 498 and LUM
1141) to find the most appropriate temperature settings for the
single-aliquot regenerative dose (SAR) procedure (Murray and Wintle, 2000).
The preheat temperatures varied from 160 to 300 <inline-formula><mml:math id="M124" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
(three aliquots per sample), with the cut-heat temperature set 40 <inline-formula><mml:math id="M125" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C lower. The results of the tests are shown in Fig. 8. There is no clear
plateau for either of the samples; between 240 and
260 <inline-formula><mml:math id="M126" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C there is not much variation, and the errors are small. It
was chosen to set the preheat to 260 <inline-formula><mml:math id="M127" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (10 s), and the OSL
read-out was conducted at 125 <inline-formula><mml:math id="M128" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for 40 s (Lx). After
administering a fixed test dose of about 7 Gy to correct for potential
sensitivity changes, the sample was heated to 220 <inline-formula><mml:math id="M129" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C,
followed by another OSL read-out at 125 <inline-formula><mml:math id="M130" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for 40 s (Tx). Each SAR
cycle ended with a blue OSL clean-out at 280 <inline-formula><mml:math id="M131" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (40 s) to minimise
recuperation (Murray and Wintle, 2003). The initial 0.4 s minus a background
of the subsequent 1.2 s was used to build the dose response curves, which
were then fitted with a single exponential function.</p>
      <p id="d1e1978">Dose recovery tests were conducted on each sample. Three aliquots per quartz
sample were bleached for 400 s with blue light, followed by a pause of
10 000 s and subsequently another 400 s illumination with blue light (inside
the Risø TL/OSL DA-20 reader). The aliquots were then given a beta dose
close to their natural dose and measured using the protocol described above.</p><?xmltex \hack{\newpage}?>
</sec>
<sec id="Ch1.S4.SS1.SSS3">
  <label>4.1.3</label><title>Testing for incomplete OSL signal resetting</title>
      <p id="d1e1990">In sedimentary settings in which transport and deposition are very rapid,
the mineral grains might not have received sufficient daylight exposure
prior to deposition. Thus, there may be a residual signal adding to the
burial dose, which would result in age overestimation. While in aeolian
sediments poor signal resetting is very unlikely (e.g. Roberts, 2008),
there may be significant residual signals in glacial and glaciofluvial
sediments (e.g. King et al., 2014).</p>
      <p id="d1e1993">Incomplete signal resetting can, for example, be investigated by (i) using a
comparison of blue light OSL and<?pagebreak page65?> infrared stimulated luminescence (IRSL)
signals (e.g. Murray et al., 2012) as these two dosimeters show different
bleaching behaviour and (ii) statistical parameters such as overdispersion
(OD) (Galbraith et al., 1999).</p>
      <p id="d1e1996">To compare the quartz OSL results with IRSL of feldspar, the post-IR IRSL
signal (Buylaert et al., 2012) on coarse-grained K-feldspar was measured on
at least three aliquots per sample, prepared with a diameter of 2 mm on
stainless steel discs. The aliquots were stimulated with IR LEDs, and the
IRSL signals were collected through a blue filter combination (Corning 7-59
and Schott BG-39) in the blue-violet region of the light spectrum. The
K-feldspar extracts were preheated at 320 <inline-formula><mml:math id="M132" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (60 s) prior to IR
(50 <inline-formula><mml:math id="M133" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, 200 s) and post-IR IR stimulation (290 <inline-formula><mml:math id="M134" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, 200 s). The test dose was set to about 50 % of the expected <inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
(calculated from quartz <inline-formula><mml:math id="M136" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, taking into account the larger dose rate to
feldspar). Dose response curves were fitted with a single exponential
function, using the initial 2 s minus a background of the last 20 s of the
decay curves. The <inline-formula><mml:math id="M137" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> ratios are listed in Table 1.</p>
      <p id="d1e2064">The overdispersion, which expresses the amount of scatter in <inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
distribution on top of the known uncertainties in measurements and analysis,
was calculated for each quartz sample using Analyst version 4.57. The values
are given as <inline-formula><mml:math id="M139" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in % and are summarised in Table 1.</p>
</sec>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><?xmltex \opttitle{${}^{{230}}$Th\,$/$\,U dating}?><title><inline-formula><mml:math id="M140" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup></mml:math></inline-formula>Th <inline-formula><mml:math id="M141" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> U dating</title>
      <p id="d1e2114">For <inline-formula><mml:math id="M142" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> dating all samples were prepared at the Leibniz Institute
for Applied Geophysics, Hanover, for isotopic measurements following the
leachate/leachate protocol of Schwarcz and Latham (1989) adopted to peat
dissolution requirements (Sierralta et al., 2012; Waas et al., 2011). A
double spike <inline-formula><mml:math id="M143" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">233</mml:mn></mml:msup><mml:mi mathvariant="normal">U</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">236</mml:mn></mml:msup><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> and a <inline-formula><mml:math id="M144" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">229</mml:mn></mml:msup></mml:math></inline-formula>Th spike were used for the
quantification of uranium and thorium contents, respectively.</p>
      <p id="d1e2161">To construct the isochrons at least three sub-samples were prepared from the
horizons of interest. Measurements were performed with a thermal ionisation
mass spectrometer (Finnigan MAT 262 RPQ) applying the double filament
technique with a peak jump routine. Mass fractionation was controlled during
measurement by the double-spike ratio <inline-formula><mml:math id="M145" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">233</mml:mn></mml:msup><mml:mi mathvariant="normal">U</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">236</mml:mn></mml:msup><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula>. All isotopic
results are given in Table S1. Activities of the isotopes were calculated
from the measured atomic ratios after normalisation to the double-spike
ratio <inline-formula><mml:math id="M146" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">233</mml:mn></mml:msup><mml:mi mathvariant="normal">U</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">236</mml:mn></mml:msup><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> to correct for the thermal fractionation. The
external reproducibility is 0.3 % (2<inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:mi mathvariant="italic">σ</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> as determined by the
measurements of the standard solution NBL U112A.</p>
</sec>
<sec id="Ch1.S4.SS3">
  <label>4.3</label><title>Pollen analysis</title>
      <p id="d1e2221">The material taken from the peat (profile 2005-2, Fig. 3) was prepared for
palynological analysis in the laboratories of the Institute of Ecology of
Leuphana University Lüneburg. About 1–3 g per sample was treated by
standard palynological methods, which included dispersion with 10 % NaOH,
carbonate removal by 10 % HCl, flotation to separate organics from the
inorganic matrix using sodium metatungstate
(3Na<inline-formula><mml:math id="M148" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> <inline-formula><mml:math id="M149" display="inline"><mml:mo>⋅</mml:mo></mml:math></inline-formula> WO<inline-formula><mml:math id="M150" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula> <inline-formula><mml:math id="M151" display="inline"><mml:mo>⋅</mml:mo></mml:math></inline-formula> 5WO<inline-formula><mml:math id="M152" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> <inline-formula><mml:math id="M153" display="inline"><mml:mo>⋅</mml:mo></mml:math></inline-formula> H<inline-formula><mml:math id="M154" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O), and acetolysis (Faegri and Iversen,
1989; Moore et al., 1991). One slide of <inline-formula><mml:math id="M155" display="inline"><mml:mrow><mml:mn mathvariant="normal">24</mml:mn><mml:mo>×</mml:mo><mml:mn mathvariant="normal">32</mml:mn></mml:mrow></mml:math></inline-formula> mm per sample was analysed
under a transmitted-light microscope for pollen, non-pollen palynomorphs, and
micro-charcoal particles at 40<inline-formula><mml:math id="M156" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> magnification. Pollen and spores were
identified using a reference collection of the Laboratory of the Institute
of Ecology, Leuphana University Lüneburg, and the atlases of Moore et al. (1991) and Beug (2004). Percentages of all recorded taxa are based on a
pollen sum composed of terrestrial taxa; pollen and spores deriving from
cryptogams, aquatic plants, Ericaceae, and Cyperaceae were excluded. Due to
bad pollen preservation the sum of 300 tree pollen per sample could not
always be achieved; only 13 samples contained a statistically solid
amount of pollen and spores. Pollen calculations for diagram construction
were performed with the software packages Tilia, Tilia Graph, and Tilia View
(Grimm, 1990).</p>
</sec>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Results</title>
<sec id="Ch1.S5.SS1">
  <label>5.1</label><title>Dose rates and luminescence data</title>
      <p id="d1e2317">The total dose rates (Table 1) for the sands range from 0.87 <inline-formula><mml:math id="M157" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.07 Gy ka<inline-formula><mml:math id="M158" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (LUM 1138) to 1.38 <inline-formula><mml:math id="M159" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.08 Gy ka<inline-formula><mml:math id="M160" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (LUM 1137; Table 1) and are
thus rather low. The low radioactivity in the sediment results in large
sensitivity to water content assumptions. We did not undertake any field or
laboratory water content measurements on our samples but put our
observations in the field in perspective to dose rate ranges presented in
the literature (Lüthgens et al., 2011; Kenzler et al., 2017;
Pisarska-Jamroży et al., 2018) and from recent stationary measurements
(tensiometer) from the Schuby station, run by the Landesamt für Landwirtschaft, Umwelt und ländliche Räume  (LLUR), Flintbek (data from
Marek Filipinski, personal communication, 2021), with absolute errors of <inline-formula><mml:math id="M161" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">5</mml:mn></mml:mrow></mml:math></inline-formula> % accounting
for changes in water content over time. Nevertheless, the uncertainty of
these assumptions on the final age may have an effect one must not lose
sight on and may bias the results.</p>
      <p id="d1e2368">The satisfactory measurement performance of equivalent dose determination is
shown by the good dose recovery test results. The mean measured to given
doses range from 0.91 <inline-formula><mml:math id="M162" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01 (LUM 1139) to 1.09 <inline-formula><mml:math id="M163" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.09 (LUM
470), with an average of 0.99 <inline-formula><mml:math id="M164" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02 (<inline-formula><mml:math id="M165" display="inline"><mml:mrow><mml:mi>n</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">8</mml:mn></mml:mrow></mml:math></inline-formula>). In addition, recycling
ratios are all within 10 % of unity, and recuperation is below 5 % for
all aliquots, implying reliable <inline-formula><mml:math id="M166" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> estimates for samples which are not
in saturation (Murray and Wintle, 2003; Wintle and Murray, 2006).</p>
      <?pagebreak page66?><p id="d1e2415">The non-saturated (i.e. <inline-formula><mml:math id="M167" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 2 <inline-formula><mml:math id="M168" display="inline"><mml:mo>⋅</mml:mo></mml:math></inline-formula> D<inline-formula><mml:math id="M169" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:math></inline-formula>; characteristic saturation
limit; Wintle and Murray, 2006) <inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>'s range from 43 <inline-formula><mml:math id="M171" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2 Gy (LUM
1141) to 88 <inline-formula><mml:math id="M172" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 7 Gy (LUM 470), resulting in ages between 43 <inline-formula><mml:math id="M173" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4 and 104 <inline-formula><mml:math id="M174" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 12 ka, respectively. For the latter sample both the
<inline-formula><mml:math id="M175" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math id="M176" display="inline"><mml:mrow><mml:mn mathvariant="normal">33.4</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2.2</mml:mn></mml:mrow></mml:math></inline-formula> % and the <inline-formula><mml:math id="M177" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> ratio of
7.09 <inline-formula><mml:math id="M178" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1.35 indicate, at first sight, very poor bleaching. In a
well-bleached setting, the <inline-formula><mml:math id="M179" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> should be 1.7 or less, taking
into account the about 0.7 Gy ka<inline-formula><mml:math id="M180" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> larger total dose rate of feldspar due to
the internal contribution of K and Rb and negligible anomalous fading for
the pIRIR<inline-formula><mml:math id="M181" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">290</mml:mn></mml:msub></mml:math></inline-formula> signal (Murray et al., 2012). Where the quartz <inline-formula><mml:math id="M182" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
approaches saturation, the <inline-formula><mml:math id="M183" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> ratio starts to deviate and
gets increasingly larger, because the OSL signal and correspondingly <inline-formula><mml:math id="M184" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
cannot grow any larger. Therefore, for samples with quartz <inline-formula><mml:math id="M185" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>s in or
close to saturation, no conclusion on the bleaching can be drawn using the
<inline-formula><mml:math id="M186" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> ratio. The same holds true for overdispersion. For a
well-bleached sample, it is generally assumed that the <inline-formula><mml:math id="M187" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is
less than 20 % (e.g. Jacobs et al., 2008). Even though these assumptions
are based on small aliquots and single grain measurements, these values may
be used as approximations for medium aliquots. According to this, poor
signal resetting may be present in sample LUM 1137, with an <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
of <inline-formula><mml:math id="M189" display="inline"><mml:mrow><mml:mn mathvariant="normal">33.5</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">3.0</mml:mn></mml:mrow></mml:math></inline-formula> % (Table 1). In addition, the OSL signal is in
saturation, resulting in a minimum age of <inline-formula><mml:math id="M190" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">70</mml:mn></mml:mrow></mml:math></inline-formula> ka. As mentioned
above, it is difficult to judge whether the large overdispersion of this
sample exclusively originates from poor bleaching. Murray et al. (2002)
illustrated that the shape and width of dose distributions change
significantly as the dose response curve approaches saturation. This effect
may be observed here. The <inline-formula><mml:math id="M191" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> ratio of 2.72 <inline-formula><mml:math id="M192" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.39 again
implies insufficient signal resetting; however, with the OSL being in
saturation the much larger pIRIR<inline-formula><mml:math id="M193" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">290</mml:mn></mml:msub></mml:math></inline-formula> <inline-formula><mml:math id="M194" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> reflected in the ratio is
not necessarily due to poor resetting but may be the true dose. A conclusion
on the effect of poor bleaching cannot be made for this sample. For all
other samples, the <inline-formula><mml:math id="M195" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is well below 30 % (Table 1). The
<inline-formula><mml:math id="M196" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math id="M197" display="inline"><mml:mrow><mml:mn mathvariant="normal">25.4</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn></mml:mrow></mml:math></inline-formula> % from the top sample of profile
2004-1 (LUM 1141) evidences the admixture of older material, as observed in
the field. The <inline-formula><mml:math id="M198" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> ratio for this sample is 2.42 <inline-formula><mml:math id="M199" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.16
and thus supports the field observations and statistical data. The
<inline-formula><mml:math id="M200" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">pIRIR</mml:mi><mml:mn mathvariant="normal">290</mml:mn></mml:msub><mml:mo>/</mml:mo><mml:mi mathvariant="normal">OSL</mml:mi></mml:mrow></mml:math></inline-formula> ratios for the other samples range from 1.49 <inline-formula><mml:math id="M201" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.07
(LUM 1139) to 1.78 <inline-formula><mml:math id="M202" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.24 (LUM 1140), indicating, together with the
<inline-formula><mml:math id="M203" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">OD</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values, good signal resetting for all those samples.</p>
</sec>
<sec id="Ch1.S5.SS2">
  <label>5.2</label><title>Dating of the peat</title>
      <p id="d1e2820">The uranium and thorium content range between 0.04–0.24 ppm and 0.12–0.64 ppm, respectively. The highest uranium content is found in the lowermost
sample. The concentration of uranium decreases upwards and slightly
increases to the top of the sampled horizons. A similar behaviour is
observed for the thorium content. The activity ratios of
<inline-formula><mml:math id="M204" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">232</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi></mml:mrow></mml:math></inline-formula> are small (1.05–1.43), thus indicating a high amount
of detrital material. Isochron dating is mandatory for such samples. The
Rosholt-type I plot showing <inline-formula><mml:math id="M205" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">232</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi></mml:mrow></mml:math></inline-formula> vs. <inline-formula><mml:math id="M206" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">234</mml:mn></mml:msup><mml:mi mathvariant="normal">U</mml:mi><mml:msup><mml:mo>/</mml:mo><mml:mn mathvariant="normal">232</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi></mml:mrow></mml:math></inline-formula>
for both the black and brown peat layers is presented in Fig. S3. The
scatter in data is large, and the best-fit line is highly variable. The
Rosholt plot therefore provides first evidence for open-system behaviour of the
two data sets. To finally check for open-system behaviour Osmond plots were
prepared and are presented in Figs. S4 and S5 (Osmond et al., 1970; Osmond and Ivanovich, 1992).
The data points scatter much wider than analytical error would suggest, and
the data imply open-system behaviour for the whole succession. Therefore, no
age calculations can be performed (Geyh, 2008).</p>
</sec>
<sec id="Ch1.S5.SS3">
  <label>5.3</label><title>Palynological zonation</title>
      <p id="d1e2888">The zonation of the pollen diagram follows the pollen zonation of Behre
(1962), Müller (1974), and Menke and Tynni (1984) for the Eemian of
northern Germany (Fig. 9). For the zone description given here, we refer
only to the subdivision of the Eemian of Rederstall (Menke and Tynni, 1984)
due to its geographical vicinity to Osterbylund. The depths given with the
zones are the sampling depths in the peat from profile 2005-2 (Fig. 3).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><?xmltex \currentcnt{9}?><?xmltex \def\figurename{Figure}?><label>Figure 9</label><caption><p id="d1e2893">Pollen diagram from the brown and black peats sampled in 2004
(profile 2005-2). Pollen calculations for diagram construction were
performed with the software packages Tilia, Tilia Graph, and Tilia View
(Grimm, 1990).</p></caption>
          <?xmltex \igopts{width=497.923228pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f09.png"/>

        </fig>

      <p id="d1e2902"><list list-type="bullet">
            <list-item>

      <p id="d1e2907">Zone E IVb (1.45–1.95 m). This part of the diagram is characterised by
high amounts of <italic>Corylus</italic> between 20 %–40 % and  <italic>Tilia</italic> (around 20 %), whereas
<italic>Taxus</italic> reaches values of about 10 %. <italic>Viscum</italic>, <italic>Ilex</italic>, <italic>Hedera helix</italic>, as well as <italic>Buxus</italic>, reach higher values in
comparison to the preceding and following zone. <italic>Quercus</italic> and <italic>Ulmus</italic> are present with
amounts below 10 %; <italic>Picea</italic> and <italic>Carpinus</italic> pollen are occurring with even smaller amounts.
In the lower part of the zone Polypodiaceae spores are abundant, and
Sphagnum spores occur with higher amounts during this zone compared to the
rest of the investigated material. Towards the top of the zone the curves of
<italic>Picea</italic> and particularly of <italic>Carpinus</italic> strongly increase, whereas <italic>Tilia</italic> drops below 10 %. During
the entire zone <italic>Alnus</italic> does not reach more than 20 %. The overlap of <italic>Tilia</italic> and
<italic>Corylus</italic> decreases, and <italic>Carpinus</italic> spread marks the upper boundary of zone E IVb.</p>
            </list-item>
            <list-item>

      <?pagebreak page67?><p id="d1e2970">Zone E V (1.45–0.75 m). This zone is strongly dominated by <italic>Carpinus</italic> (up to
40 %), decreasing towards the top of the zone, and by <italic>Picea</italic> which increases
parallel to the drop of <italic>Carpinus</italic>. The amounts of <italic>Betula</italic> have increased up to 20 %,
whereas <italic>Corylus</italic> has dropped below about 5 %, disappearing entirely towards the
top of the zone. <italic>Alnus</italic> is increasing (up to 40 %) in the lower part of the zone
and decreasing towards its top. <italic>Abies</italic> is found to occur continuously from about
the middle part of the zone. <italic>Quercus</italic> slightly increases again towards the top of
zone. <italic>Taxus</italic> is found in small amounts associated with the start of the <italic>Abies</italic> curve.
<italic>Ilex</italic>, <italic>Viscum</italic>, and <italic>Buxus</italic> are only present in small amounts. <italic>Myrica</italic> and Ericaceae, mainly <italic>Calluna</italic>, as well
as Poaceae and further non-arboreal pollen (NAP), increase as well.
Ascomycete spores and the sum of unidentified spores, probably deriving
from mosses, reach rather high values. The upper boundary of Zone V is drawn
at the drop of the <italic>Carpinus</italic> curve below 10 % and the increase of <italic>Picea</italic>, <italic>Pinus</italic>, and <italic>Abies</italic>.</p>
            </list-item>
            <list-item>

      <p id="d1e3036">Zone E VI (0.05–0.75 m). The youngest pollen zone of the peat layer is
mainly characterised by <italic>Picea</italic>, <italic>Pinus</italic>, <italic>Abies</italic>, and <italic>Betula</italic>. <italic>Picea</italic> reaches high amounts of about 40 %,
and the <italic>Pinus</italic> curve is only increasing towards the top of the zone. The curves of
<italic>Ulmus</italic>, <italic>Quercus</italic>, and <italic>Carpinus</italic> dropped down to 1 % and below 1 %. <italic>Alnus</italic> is still
present with lower amounts of around 10 %. Within the NAP the first
occurrence of <italic>Artemisia</italic> is as notable as a remarkable increase of <italic>Calluna</italic> of up to nearly 20 %.</p>
            </list-item>
          </list></p>
</sec>
</sec>
<sec id="Ch1.S6">
  <label>6</label><title>Discussion</title>
      <p id="d1e3088">The correlation between the individual profiles is based on the humic layers
representing palaeosols (OBL 1–4) and the OSL ages. The sedimentological
investigations in 2016 lead to the conclusion that the lower diamicton is a
subglacial traction till (Evans et al., 2006) deposited during a Saalian
advance of the Scandinavian Ice Sheet. The sand lenses present (Figs. 5 and
6) could either be formed by supraglacial, englacial, or subglacial drainage
systems and had been subsequently incorporated into the till. The faintly
stratified upper part of unit I (Fig. 6) could either be a supraglacial
melt-out till (Lukas and Rother, 2016) or the result of periglacial
reworking processes after or during an ice decaying phase.</p>
      <p id="d1e3091">OBL 1 is to be correlated with the up to 2 m thick peat found during the
excavations in profiles 2003 and 2005-2, filling a depression on the surface
of the till (see Figs. 2 and 3). Due to the open-system behaviour of the
peat, no <inline-formula><mml:math id="M207" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> ages can be presented. The OSL age of 86 <inline-formula><mml:math id="M208" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8 ka (LUM 1138; Fig. 3) from well-bleached sediments well above OBL 1 shows that
the peat is older than the Odderade interstadial (Fig. 10). The
corresponding sample LUM 470 is poorly bleached and cannot add any
information. Further age constraint is exclusively provided by the pollen
analysis, as the OSL sample (LUM 1137) underlying the peat is<?pagebreak page68?> both poorly
bleached and saturated; no accurate age can be presented for this sample.</p>
      <p id="d1e3117">The onset of the <italic>Corylus</italic>, <italic>Tilia</italic>, and <italic>Taxus</italic> curves and the maximum distribution of <italic>Corylus</italic>
characteristic for Eemian pollen zone E IVa (Menke and Tynni, 1984) are not
recorded in the peat layer of Osterbylund. Peat growth at the investigated
location started only during the second half of pollen zone IV, the <italic>Tilia</italic> phase
of Menke and Tynni (1984) which is characterised by the dominance of <italic>Tilia</italic> and of
<italic>Corylus</italic>, next to <italic>Ulmus</italic> and <italic>Quercus</italic>. <italic>Taxus </italic>only reaches  values of about 10 % during E IVb at
Osterbylund, further indicating that peat growth started only after the
pronounced <italic>Taxus</italic> phase (Menke and Tynni, 1986) during the younger part of zone IVb.
This zone corresponds to pollen zone IVb of Behre (1962) and Müller (1974), respectively. According to varve counts of Eemian deposits at
Munster-Breloh and estimates of the duration of pollen zones of Müller (1974), zone IVb should have had a duration of 1100 years.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F10"><?xmltex \currentcnt{10}?><?xmltex \def\figurename{Figure}?><label>Figure 10</label><caption><p id="d1e3157">Oxygen isotope curve (NGRIP Community Members, 2004) showing the
marine isotope stages (MIS) and Late Pleistocene subdivision. After the
Eemian (5e; OBL 1) three phases warm enough for soil formation
(interstadials) are present and in Osterbylund represented by palaeosols:
Brörup <inline-formula><mml:math id="M209" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> OBL 2, Odderade <inline-formula><mml:math id="M210" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> OBL 3, and Keller <inline-formula><mml:math id="M211" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> OBL 4.</p></caption>
        <?xmltex \igopts{width=227.622047pt}?><graphic xlink:href="https://egqsj.copernicus.org/articles/72/57/2023/egqsj-72-57-2023-f10.png"/>

      </fig>

      <p id="d1e3187">The following zone, which seems to be fully preserved, corresponds to the
<italic>Carpinus</italic> zone E V (Menke and Tynni, 1984) and can be correlated with pollen zones Va
and Vb of Müller (1974). The occurrence of <italic>Viscum</italic>, <italic>Hedera helix</italic>, and <italic>Buxus</italic> in this and the
following zones has been recorded from other western European Eemian sites
(Litt, 1994; Zagwijn, 1996; Kühl and Litt, 2007) including adjacent areas
from northern Germany (Behre, 1962; Behre and Lade, 1986; Müller, 1974;
Menke and Tynni, 1984; Ziemus, 1989; Behre et al., 2005) and characterises
the thermal optimum of the interglacial. Müller (1974) has estimated the
duration of zone E V, Va and Vb, to about 4000 years.</p>
      <p id="d1e3202">The youngest recorded pollen zone in Osterbylund, correlated with zone E VI
(Menke and Tynni, 1984) and zone VI of Müller (1974), shows a decrease
of deciduous thermophilous trees and the expansion of <italic>Picea</italic>, <italic>Pinus</italic>, <italic>Abies</italic>, and <italic>Betula</italic>, marking the
beginning of the termination of the interglacial. The overrepresentation of
<italic>Picea</italic> in the profile of Osterbylund compared to other profiles from northern
Germany might be caused by local peat bog conditions favouring spruce-rich
forest swamps (Menke and Tynni, 1984). This interpretation and the large
occurrence of <italic>Calluna</italic> in the upper zone from about 0.75 m upwards are in agreement
with a change in peat composition. Compared to central or southern German
locations (Grüger, 1979; Urban et al., 1991; Litt, 1994; Litt et al.,
1996), the relative low representation of <italic>Abies</italic> during this late interglacial
phase at Osterbylund and at other northern German sites, e.g. Lichtenberg
(Veil et al., 1994; Hein et al., 2021), is caused by the northern limit of
the distribution area of <italic>Abies</italic> which lay in Jutland during that time (Zagwijn,
1989). The transition to pollen zone VII and the entire pollen zone VII, representing the
end of the interglacial, are not recorded as the uppermost part of the peat
has been eroded. Müller (1974) estimated the duration of Eemian pollen Zone
VI (E VI after Menke and Tynni, 1984) to about 1000 years, whereas Kühl
and Litt (2007) published a revised extrapolation of 2000 years.</p>
      <p id="d1e3230">According to these time estimates, the duration of the Eemian peat layer
formation at Osterbylund, which comprises pollen zones E IVb, E V, and most
parts of E VI (Menke and Tynni, 1984; Müller, 1974), can roughly be
estimated to about 6000 years. Turner (2002) pointed out that the entire
duration of the terrestrial Eemian north of the Alps or Pyrenees was less
than 13 000 years, which matches the results of Urban (2007)
who proposed a duration of 10 ka for pollen zones E1–E6 of the Eemian <italic>sensu stricto</italic>
(Zagwijn, 1961) and 10 000 years for the entire interglacial.
The terrestrial Eemian has been correlated with MIS5e of the deep-sea
chronology (Shackleton, 1969, Mangerud et al., 1979; Fig. 10) and spans
the time between about 126 to 115 ka (summarised in Urban,
2007). The age of the peat layer of Osterbylund therefore can be estimated
to be about 120 ka.</p>
      <p id="d1e3236">The reworking of the OBL 1 palaeosol will thus have occurred after MIS5e.
Due to the soil formation processes and the resulting post-depositional
changes, the interpretation of the depositional environment cannot be
reconstructed unambiguously. Slope movements under periglacial conditions
are conceivable (Stephan et al., 2017), which filled<?pagebreak page69?> former depressions
of the landscape topography (Guerra et al., 2017). In addition, denudation
processes may have partly contributed to the deposition, at least of
the lower and middle part of unit II (Fig. 6). In this context, the
occurrence of channel-like structures filled with granules is of
importance. The better sorting of the upper sandy part of unit II might
indicate that  aeolian processes have also contributed to the deposition. In
unit II the Ah horizon at the top (<inline-formula><mml:math id="M212" display="inline"><mml:mo lspace="0mm">=</mml:mo></mml:math></inline-formula> OBL 2) illustrates a halt in
sedimentation and consequently a hiatus; at least some erosion of the former
Ah horizon is likely. The age of 86 <inline-formula><mml:math id="M213" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 8 ka (LUM 1138, Fig. 3) from
just below OBL 2 puts the formation of this palaeosol either into the
Brörup or the Odderade interstadial (Fig. 10). Considering that there is
no indication of a hiatus, it is more likely that OBL 2 is to be correlated
with the Brörup interstadial.</p>
      <p id="d1e3253">The formation of unit III (Fig. 6), which brackets OBL 2 and OBL 3 (Figs. 3
and 4), is probably related to slope movements (Stephan et al., 2017, and
their Fig. 7) under periglacial conditions (Millar, 2013). Especially soft
sediment deformation structures indicate gravity-induced failures along the
basin slope (Blair and McPherson, 2009). This assumption is supported by the
outsized clasts within the upper part of this sand package, which have been
transported downslope. Furthermore, the sand-filled cracks and fissures
suggest freeze–thaw action and the existence of permafrost and thus
subarctic conditions. The seasonal thawing of the active layer induced frost
creeping of larger stones and boulders down the slope. Some of these
boulders show fragmentation due to volume expansion of freezing water in
fissures. This clearly implies cold climate conditions during the deposition
of the sandy part of this unit. OBL 3 developed most likely under an
interstadial climate after 69 <inline-formula><mml:math id="M214" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 ka (LUM 1139), which is the age of
the underlying sand. The equivalent sample LUM 469 was dated to 68 <inline-formula><mml:math id="M215" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 ka, supporting the age constrain. According to these dating results, one
could assign the soil formation to either the Odderade or Keller
interstadial (Fig. 10).</p>
      <p id="d1e3271">Above the OBL 3 palaeosol there are aeolian sands, for which good OSL signal
resetting had to be expected. While the age of 60 <inline-formula><mml:math id="M216" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 6 ka (LUM 1140)
just below the humic horizon of OBL 4 (Fig. 3) seems reliable according to
the OSL testing and statistical parameters, the sand covering the palaeosol
was poorly bleached, which results in a possibly overestimated age of 43 <inline-formula><mml:math id="M217" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 4 ka (LUM 1141). If that age was the true depositional age, it would
fall into MIS3, thus implying a significant hiatus, for which no field
evidence was present. From the sedimentological observations it is not
possible to reconstruct a distinct depositional environment to these sands
(Fig. 6). The burrow-like structures across this unit display the
occurrence of digging animals such as rodents. If true, this could indicate
a tundra-steppe ecosystem in a periglacial landscape (Dupal et al., 2013).
This assumption is supported by the existence of ice wedge casts. If such an
ice wedge was accidentally sampled, even younger material than
representative for the sandy layer could have been sampled. It is therefore
not possible to finally conclude on the age of the sand overlying OBL 4.</p>
      <p id="d1e3288">However, there are no phases warm enough for soil formation during this
period, and despite this unknown, assignment of this humic horizon to the
Keller interstadial (Fig. 10) seems feasible, thereby assigning OBL 3 to the
Odderade interstadial. The sandy deposits of the upper section of unit VI
would therefore belong to the Ellund cold phase or even younger (Fig. 10).</p>
      <p id="d1e3291">Because of the unequivocal palynological assignment of the peat to the
Eemian, an upper limit to the age of the palaeosols (OBL 2–4) above the peat
is clear. Thus, the entire push moraine complex (Fig. 1) has to be of
Saalian age. This observation makes  a Weichselian glacial margin
even further west unlikely, i.e. south of the Danish border, as discussed by
Houmark-Nielsen (2007). All palaeosols formed during the early Weichselian
(MIS 5a–d), which is in agreement with the observations of Gripp et al. (1965). While the pollen data provide a clear view on the age of OBL 1, the
luminescence data cannot be interpreted unambiguously; they have to be seen
in their entirety and not on their own.</p>
</sec>
<sec id="Ch1.S7" sec-type="conclusions">
  <label>7</label><title>Conclusions</title>
      <p id="d1e3302">The aim of this study was not only to unravel the age of the push moraine
complex Wallsbüll-Böxlund, Schleswig-Holstein, but also to assign
the peat and palaeosols present in depressions in Osterbylund to
interglacials and interstadials in order to add another jigsaw piece to the
understanding of the glacial history in the western Baltic region.</p>
      <p id="d1e3305">The attempt to date the peat layers using <inline-formula><mml:math id="M218" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> dating failed due to
the open-system behaviour of both the brown and the black peat. However, the
pollen analyses allowed for clear assignment of the peat and thus of the
palaeosol OBL 1 to the Eemian. This coincides with the saturated and
correspondingly old age of the sands underlying the peat; the sands above
the peat were dated to the early Weichselian. While for palaeosol OBL 2 the
assignment to the Brörup interstadial is clear, the correlation of the
palaeosols OBL 3 and OBL 4 to any interstadial is hampered due to the
limited luminescence data available. Poor luminescence signal resetting
especially of the sands above OBL 4 makes an assessment of an upper limit
for the palaeosol formation difficult. However, from the field, as well as
luminescence data, it is most likely that OBL 3 formed during the Odderade
interstadial and OBL 4 during the Keller interstadial. This observation
contrasts previous findings claiming that only two post-Eemian thermomers,
i.e. Brörup and Odderade interstadials, are to be expected due to the
insolation of the Northern Hemisphere. The weakly developed OBL 4 seems to
indicate though that warm oceanic currents in the North Atlantic and
correspondingly in northern Germany resulted in another – terrestrial –
third weak thermomer and is thus not unique to marine settings and ice
cores.</p>
      <?pagebreak page70?><p id="d1e3324"><?xmltex \hack{\newpage}?>With Eemian up to early Weichselian ages of the peat and palaeosols, filling the depression it is evident that the push moraine
complex is of Saalian age; a Weichselian ice margin further in the west as
assumed in other studies is therefore unlikely. It is certainly worth
investigating the position and ages of the Weichselian ice margins in the
future as this would complement the studies from Denmark and NE Germany.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e3332">Data are available from the authors upon request.</p>
  </notes><notes notes-type="sampleavailability"><title>Sample availability</title>

      <p id="d1e3339">Treated and untreated material for luminescence dating, as well as dose rate
samples, are stored at the Leibniz Institute for Applied Geophysics.
Remaining material from the peat is stored at both Leibniz Institute for
Applied Geophysics (<inline-formula><mml:math id="M219" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> dating) and Leuphana University
Lüneburg (pollen analysis).</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d1e3358">The supplement related to this article is available online at: <inline-supplementary-material xlink:href="https://doi.org/10.5194/egqsj-72-57-2023-supplement" xlink:title="pdf">https://doi.org/10.5194/egqsj-72-57-2023-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e3367">HJS and MF initiated the study. HSJ, MF, MS, BU, and MK investigated the
sites in the field and took samples. CT undertook the luminescence dating.
MS was responsible for <inline-formula><mml:math id="M220" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi/><mml:mn mathvariant="normal">230</mml:mn></mml:msup><mml:mi mathvariant="normal">Th</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">U</mml:mi></mml:mrow></mml:math></inline-formula> dating. BU analysed and interpreted the
pollen. CT and HJS prepared the manuscript with contributions from MS, BU,
and MK.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e3389">The contact author has declared that none of the authors has any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e3395">Publisher’s note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e3401">The technical assistance of Sonja Riemenschneider, Gudrun Drewes, Sabine
Mogwitz, and Petra Posimowski (LIAG) is very much appreciated. Margot Böse and Tony Reimann are thanked for
their constructive comments, which helped to improve the manuscript.
Christopher Lüthgens is thanked for the editorial handling.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e3406">This research has been supported by the Deutsche Forschungsgemeinschaft (grant no. KE 2023/2–1).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e3412">This paper was edited by Christopher Lüthgens and reviewed by Margot Böse and Tony Reimann.</p>
  </notes><?xmltex \hack{\newpage}?><ref-list>
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