Articles | Volume 71, issue 1
https://doi.org/10.5194/egqsj-71-83-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/egqsj-71-83-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
18O analyses of bulk lipids as novel paleoclimate tool in loess research – a pilot study
Jakob Labahn
CORRESPONDING AUTHOR
Heisenberg Chair of Physical Geography with Focus on Paleoenvironmental
Research, Technische Universität Dresden, Helmholtzstraße 10, 01069
Dresden, Germany
Lucas Bittner
Heisenberg Chair of Physical Geography with Focus on Paleoenvironmental
Research, Technische Universität Dresden, Helmholtzstraße 10, 01069
Dresden, Germany
Philip Hirschmann
Heisenberg Chair of Physical Geography with Focus on Paleoenvironmental
Research, Technische Universität Dresden, Helmholtzstraße 10, 01069
Dresden, Germany
Christopher-Bastian Roettig
Heisenberg Chair of Physical Geography with Focus on Paleoenvironmental
Research, Technische Universität Dresden, Helmholtzstraße 10, 01069
Dresden, Germany
Diana Burghardt
Institute of Groundwater Management, Department of Hydro Sciences,
Technische Universität Dresden, Bergstraße 66, 01069 Dresden,
Germany
Bruno Glaser
Soil Biogeochemistry, Institute of Agronomy and Nutritional Sciences,
Martin Luther University Halle-Wittenberg, Von-Seckendorff-Platz 3, 06120
Halle (Saale), Germany
Slobodan B. Marković
Chair of Physical Geography, Faculty of Sciences, University of Novi Sad, Trg D. Obradovića 3, 21000 Novi Sad, Serbia
Michael Zech
CORRESPONDING AUTHOR
Heisenberg Chair of Physical Geography with Focus on Paleoenvironmental
Research, Technische Universität Dresden, Helmholtzstraße 10, 01069
Dresden, Germany
Related authors
No articles found.
Fabian Seemann, Michael Zech, Maren Jenrich, Guido Grosse, Benjamin M. Jones, Claire Treat, Lutz Schirrmeister, Susanne Liebner, and Jens Strauss
EGUsphere, https://doi.org/10.5194/egusphere-2025-3727, https://doi.org/10.5194/egusphere-2025-3727, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
Arctic coastal landscapes, like those in northernmost Alaska, often contain saline sediments that are more prone to thawing. We studied six sediment cores to understand how thawing and salinity affect organic carbon breakdown and land change. Our results show that salinity speeds up organic matter loss when permafrost thaws. This highlights the overlooked risk of salinity in shaping Arctic landscapes and carbon release as the climate continues to warm.
Lucas Bittner
E&G Quaternary Sci. J., 73, 135–137, https://doi.org/10.5194/egqsj-73-135-2024, https://doi.org/10.5194/egqsj-73-135-2024, 2024
Lucas Bittner, Cindy De Jonge, Graciela Gil-Romera, Henry F. Lamb, James M. Russell, and Michael Zech
Biogeosciences, 19, 5357–5374, https://doi.org/10.5194/bg-19-5357-2022, https://doi.org/10.5194/bg-19-5357-2022, 2022
Short summary
Short summary
With regard to global warming, an understanding of past temperature changes is becoming increasingly important. Branched glycerol dialkyl glycerol tetraethers (brGDGTs) are membrane lipids used globally to reconstruct lake water temperatures. In the Bale Mountains lakes, we find a unique composition of brGDGT isomers. We present a modified local calibration and a new high-altitude temperature reconstruction from the Horn of Africa spanning the last 12.5 kyr.
Marcel Lerch, Julia Unkelbach, Florian Schneider, Michael Zech, and Michael Klinge
E&G Quaternary Sci. J., 71, 91–110, https://doi.org/10.5194/egqsj-71-91-2022, https://doi.org/10.5194/egqsj-71-91-2022, 2022
Short summary
Short summary
Charcoals and leaf waxes from vegetation accumulate in the soil and provide information about past vegetation because they are mostly resistant against physical and biological degradation. Analyzing and comparing ratios of both element types helped us to improve the evidence for vegetation reconstruction. We found that the accumulation processes and preservation of these elements depend on different environmental conditions at forest- and steppe-dominated sites in the Mongolian forest–steppe.
Marcel Lerch, Tobias Bromm, Clemens Geitner, Jean Nicolas Haas, Dieter Schäfer, Bruno Glaser, and Michael Zech
Biogeosciences, 19, 1135–1150, https://doi.org/10.5194/bg-19-1135-2022, https://doi.org/10.5194/bg-19-1135-2022, 2022
Short summary
Short summary
Faecal biomarker analyses present a useful tool in geoarcheological research. For a better understanding of the lives of our ancestors in alpine regions, we investigated modern livestock faeces and Holocene soils at the prehistorical encampment site of Ullafelsen in the Fotsch Valley, Stubai Alps, Austria. Initial results show a high input of livestock faeces and a negligible input of human faeces for this archeological site. Future studies will focus on mire archives in the Fotsch Valley.
Johannes Hepp, Christoph Mayr, Kazimierz Rozanski, Imke Kathrin Schäfer, Mario Tuthorn, Bruno Glaser, Dieter Juchelka, Willibald Stichler, Roland Zech, and Michael Zech
Biogeosciences, 18, 5363–5380, https://doi.org/10.5194/bg-18-5363-2021, https://doi.org/10.5194/bg-18-5363-2021, 2021
Short summary
Short summary
Deriving more quantitative climate information like relative air humidity is one of the key challenges in paleostudies. Often only qualitative reconstructions can be done when single-biomarker-isotope data are derived from a climate archive. However, the coupling of hemicellulose-derived sugar with leaf-wax-derived n-alkane isotope results has the potential to overcome this limitation and allow a quantitative relative air humidity reconstruction.
Michael Zech, Marcel Lerch, Marcel Bliedtner, Tobias Bromm, Fabian Seemann, Sönke Szidat, Gary Salazar, Roland Zech, Bruno Glaser, Jean Nicolas Haas, Dieter Schäfer, and Clemens Geitner
E&G Quaternary Sci. J., 70, 171–186, https://doi.org/10.5194/egqsj-70-171-2021, https://doi.org/10.5194/egqsj-70-171-2021, 2021
Christopher Lüthgens, Daniela Sauer, and Michael Zech
E&G Quaternary Sci. J., 69, 261–262, https://doi.org/10.5194/egqsj-69-261-2021, https://doi.org/10.5194/egqsj-69-261-2021, 2021
Christopher-Bastian Roettig
E&G Quaternary Sci. J., 69, 161–163, https://doi.org/10.5194/egqsj-69-161-2020, https://doi.org/10.5194/egqsj-69-161-2020, 2020
Cited articles
Bittner, L., Gil-Romera, G., Grady, D., Lamb, H., Lorenz, E., Weiner, M.,
Meyer, H., Bromm, T., Glaser, B., and Zech, M.: The Holocene
lake-evaporation history of the afro-alpine Lake Garba Guracha in the Bale
Mountains, Ethiopia, based on δ18O records of sugar biomarker
and diatoms, Quaternary Res., 105, 23–36, https://doi.org/10.1017/qua.2021.26, 2021.
Dansgaard, W.: Stable isotopes in precipitation, Tellus, 16, 436–468,
https://doi.org/10.1111/j.2153-3490.1964.tb00181.x, 1964.
Farquhar, G. D. and Lloyd, J.: 5 – Carbon and Oxygen Isotope Effects in the
Exchange of Carbon Dioxide between Terrestrial Plants and the Atmosphere,
in: Stable Isotopes and Plant Carbon-water Relations, edited by: Ehleringer,
J. R., Hall, A. E., and Farquhar, G. D., Academic Press, San Diego, 47–70,
https://doi.org/10.1016/B978-0-08-091801-3.50011-8, 1993.
Ferrio, J. P., Pou, A., Florez-Sarasa, I., Gessler, A., Kodama, N., Flexas,
J., and Ribas-Carbo, M.: The Péclet effect on leaf water enrichment
correlates with leaf hydraulic conductance and mesophyll conductance for
CO2, Plant, Cell Environ., 35, 611–625,
https://doi.org/10.1111/j.1365-3040.2011.02440.x, 2012.
Häggi, C., Eglinton, T. I., Zech, W., Sosin, P., and Zech, R.: A 250 ka
leaf-wax δD record from a loess section in Darai Kalon, Southern
Tajikistan, Quaternary Sci. Rev., 208, 118–128,
https://doi.org/10.1016/j.quascirev.2019.01.019, 2019.
Lachniet, M. S.: Climatic and environmental controls on speleothem
oxygen-isotope values, Quaternary Sci. Rev., 28, 412–432,
https://doi.org/10.1016/j.quascirev.2008.10.021, 2009.
Lehmkuhl, F., Nett, J. J., Pötter, S., Schulte, P., Sprafke, T., Jary,
Z., Antoine, P., Wacha, L., Wolf, D., Zerboni, A., Hošek, J.,
Marković, S. B., Obreht, I., Sümegi, P., Veres, D., Zeeden, C.,
Boemke, B., Schaubert, V., Viehweger, J., and Hambach, U.: Loess landscapes
of Europe – Mapping, geomorphology, and zonal differentiation,
Earth-Sci. Rev., 215, 103496,
https://doi.org/10.1016/j.earscirev.2020.103496, 2021.
Lemma, B., Bittner, L., Glaser, B., Kebede, S., Nemomissa, S., Zech, W., and
Zech, M.: δ2Hn−alkane and δ18Osugar
biomarker proxies from leaves and topsoils of the Bale Mountains, Ethiopia,
and implications for paleoclimate reconstructions, Biogeochem., 153,
https://doi.org/10.1007/s10533-021-00773-z, 2021.
Lisiecki, L. E. and Raymo, M. E.: A Pliocene-Pleistocene stack of 57
globally distributed benthic δ18O records, Paleoceanography, 20,
https://doi.org/10.1029/2004PA001071, 2005.
Marković, S., Stevens, T., Kukla, G., Hambach, U., Fitzsimmons, K.,
Gibbard, P., Buggle, B., Zech, M., Guo, Z., Hao, Q., Wu, H., O'Hara-Dhand,
K., Smalley, I., Újvári, G., Sümegi, P., Timar-Gabor, A., Veres,
D., Sirocko, F., Vasiljevic, D., Vidojko, J., Zdzislaw, J., Anderss, S.,
Lehmkuhl, F., Kovács, J., and Svirčev, Z.: Danube loess stratigraphy
– Towards a pan-European loess stratigraphic model, Earth-Sci. Rev.,
148, 228–258, https://doi.org/10.1016/j.earscirev.2015.06.005, 2015.
Maxwell, T. M., Silva, L. C. R., and Horwath, W. R.: Predictable Oxygen
Isotope Exchange Between Plant Lipids and Environmental Water: Implications
for Ecosystem Water Balance Reconstruction, J. Geophys. Res.-Biogeosc., 123, 2941–2954,
https://doi.org/10.1029/2018JG004553, 2018.
NGRIP members: High-resolution record of Northern Hemisphere climate
extending into the last interglacial period, Nature, 431, 147–151,
https://doi.org/10.1038/nature02805, 2004.
Peel, M. C., Finlayson, B. L., and McMahon, T. A.: Updated world map of the Köppen-Geiger climate classification, Hydrol. Earth Syst. Sci., 11, 1633–1644, https://doi.org/10.5194/hess-11-1633-2007, 2007.
Prud'homme, C., Lécuyer, C., Antoine, P., Moine, O., Hatté, C.,
Fourel, F., Martineau, F., and Rousseau, D.-D.: Palaeotemperature
reconstruction during the Last Glacial from δ18O of earthworm
calcite granules from Nussloch loess sequence, Germany, Earth Planet.
Sci. Lett., 442, 13–20, https://doi.org/10.1016/j.epsl.2016.02.045,
2016.
Pustovoytov, K. and Terhorst, B.: An isotopic study of a late Quaternary
loess-paleosol sequence in SW Germany, Revista mexicana de ciencias
geológicas, ISSN 1026-8774, Vol. 21, No. 1, 2004 (Ejemplar dedicado
a: VI International Symposium and Field Workshop on Paleopedology), 21, 88–93 pp., 2004.
Roden, J. S., Lin, G., and Ehleringer, J. R.: A mechanistic model for
interpretation of hydrogen and oxygen isotope ratios in tree-ring cellulose,
Geochim. Cosmochim. Acta, 64, 21–35,
https://doi.org/10.1016/S0016-7037(99)00195-7, 2000.
Schäfer, I., Bliedtner, M., Wolf, D., Faust, D., and Zech, R.: Evidence
for humid conditions during the last glacial from leaf wax patterns in the
loess–paleosol sequence El Paraíso, Central Spain, Quaternary
Int., 407, 64–73, https://doi.org/10.1016/j.quaint.2016.01.061, 2016.
Schmidt, H. L., Werner, R. A., and Rossmann, A.: 18O pattern and
biosynthesis of natural plant products, Phytochemistry, 58, 9–32,
https://doi.org/10.1016/s0031-9422(01)00017-6, 2001.
Silva, L. C. R., Pedroso, G., Doane, T. A., Mukome, F. N. D., and Horwath,
W. R.: Beyond the cellulose: Oxygen isotope composition of plant lipids as a
proxy for terrestrial water balance, Geochem. Perspect.
Lett., 33–42, https://doi.org/10.7185/geochemlet.1504, 2015.
Sirocko, F., Knapp, H., Dreher, F., Foerster, M., Albert, J., Brunck, H.,
Veres, D., Dietrich, S., Zech, M., Hambach, U., Röhner, M., Rudert, S.,
Schwibus, K., Adams, C., and Sigl, P.: The ELSA-Vegetation-Stack:
Reconstruction of Landscape Evolution Zones (LEZ) from laminated Eifel maar
sediments of the last 60,000 years, Global Planet. Change, 148,
108–135, https://doi.org/10.1016/j.gloplacha.2016.03.005, 2016.
Spötl, C., Mangini, A., and Richards, D. A.: Chronology and
paleoenvironment of Marine Isotope Stage 3 from two high-elevation
speleothems, Austrian Alps, Quaternary Sci. Rev., 25, 1127–1136,
https://doi.org/10.1016/j.quascirev.2005.10.006, 2006.
Stevens, T., Marković, S. B., Zech, M., Hambach, U., and Sümegi, P.:
Dust deposition and climate in the Carpathian Basin over an independently
dated last glacial–interglacial cycle, Quaternary Sci. Rev., 30,
662–681, https://doi.org/10.1016/j.quascirev.2010.12.011, 2011.
Zech, M., Tuthorn, M., Detsch, F., Rozanski, K., Zech, R., Zöller, L.,
Zech, W., and Glaser, B.: A 220ka terrestrial δ18O and
deuterium excess biomarker record from an eolian permafrost paleosol
sequence, NE-Siberia, Complete, 220–230,
https://doi.org/10.1016/j.chemgeo.2013.10.023, 2013.
Zech, M., Mayr, C., Tuthorn, M., Leiber-Sauheitl, K., and Glaser, B.: Oxygen
isotope ratios (18O/16O) of hemicellulose-derived sugar biomarkers
in plants, soils and sediments as paleoclimate proxy I: Insight from a
climate chamber experiment, Geochim. Cosmochim. Acta, 126, 614–623,
https://doi.org/10.1016/j.gca.2013.10.048, 2014.
Zech, M., Zech, R., Rozanski, K., Gleixner, G., and Zech, W.: Do n-alkane
biomarkers in soils/sediments reflect the δ2H isotopic
composition of precipitation? A case study from Mt. Kilimanjaro and
implications for paleoaltimetry and paleoclimate research, Isotop. Environ. Health Stud., 51, 508–524,
https://doi.org/10.1080/10256016.2015.1058790, 2015.
Zech, R., Zech, M., Marković, S., Hambach, U., and Huang, Y.: Humid
glacials, arid interglacials? Critical thoughts on pedogenesis and
paleoclimate based on multi-proxy analyses of the loess–paleosol sequence
Crvenka, Northern Serbia, Palaeogeogr. Palaeoclim. Palaeoecol.,
387, 165–175, https://doi.org/10.1016/j.palaeo.2013.07.023, 2013.